An Odor Interaction Model of Binary Odorant Mixtures by a Partial Differential Equation Method

نویسندگان

  • Luchun Yan
  • Jiemin Liu
  • Guihua Wang
  • Chuandong Wu
چکیده

A novel odor interaction model was proposed for binary mixtures of benzene and substituted benzenes by a partial differential equation (PDE) method. Based on the measurement method (tangent-intercept method) of partial molar volume, original parameters of corresponding formulas were reasonably displaced by perceptual measures. By these substitutions, it was possible to relate a mixture's odor intensity to the individual odorant's relative odor activity value (OAV). Several binary mixtures of benzene and substituted benzenes were respectively tested to establish the PDE models. The obtained results showed that the PDE model provided an easily interpretable method relating individual components to their joint odor intensity. Besides, both predictive performance and feasibility of the PDE model were proved well through a series of odor intensity matching tests. If combining the PDE model with portable gas detectors or on-line monitoring systems, olfactory evaluation of odor intensity will be achieved by instruments instead of odor assessors. Many disadvantages (e.g., expense on a fixed number of odor assessors) also will be successfully avoided. Thus, the PDE model is predicted to be helpful to the monitoring and management of odor pollutions.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Research on Odor Interaction between Aldehyde Compounds via a Partial Differential Equation (PDE) Model

In order to explore the odor interaction of binary odor mixtures, a series of odor intensity evaluation tests were performed using both individual components and binary mixtures of aldehydes. Based on the linear relation between the logarithm of odor activity value and odor intensity of individual substances, the relationship between concentrations of individual constituents and their joint odo...

متن کامل

VLE Predictions of Strongly Non-Ideal Binary Mixtures by Modifying Van Der Waals and Orbey-Sandler Mixing Rules

By proposing a predictive method with no adjustable parameter and by using infinite dilution activity coefficients of components in binary mixtures obtained from UNIFAC model, the binary interaction parameters (k12) in van der Waals mixing rule (vdWMR) and Orbey-Sandler mixing rule (OSMR) have been evaluated. The predicted binary interaction parameters are used in Peng-Robinson-S...

متن کامل

A New Surface Tension Model for Prediction of Interaction Energy between Components and Activity Coefficients in Binary Systems

In this work, we develop a correlative model based on the surface tension data in order to calculate thermodynamic parameters, such as interaction energy between components (Uij), activity coefficients and etc. In the new approach, by using Li et al. (LWW) model, a three-parameter surface tension equation is derived for liquid mixtures. The surface tension data of 54 aqueous and 73 non-aqueous ...

متن کامل

Correlations and Predictions of THF + 2-Alkanol Binary Mixtures Behaviour by PC-SAFT Model and Friction Theory

In this article the behavior of tetrahydrofuran (THF) + 2-alkanol namely 2-propanol, 2-butanol, 2-pentanol, 2-hexanol and 2-heptanol binary mixtures through the density and viscosity measurements have been studied as a function of composition and within the temperature range of 293.15–313.15 K. The excess molar volume, isobaric thermal expansivity, partial molar volumes, and viscosity deviation...

متن کامل

Use of a Modified Vector Model for Odor Intensity Prediction of Odorant Mixtures

Odor intensity (OI) indicates the perceived intensity of an odor by the human nose, and it is usually rated by specialized assessors. In order to avoid restrictions on assessor participation in OI evaluations, the Vector Model which calculates the OI of a mixture as the vector sum of its unmixed components' odor intensities was modified. Based on a detected linear relation between the OI and th...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 14  شماره 

صفحات  -

تاریخ انتشار 2014